Convenient and large-scale fabrication of cost-effective superhydrophobic aluminum alloy surface with excellent reparability

Langmuir. 2021 Jun 29;37(25):7810-7820. doi: 10.1021/acs.langmuir.1c01123. Epub 2021 Jun 15.

Abstract

Superhydrophobic surfaces are widely used in industry and daily life, yet their practical application is limited by their complicated preparation process, high cost, and poor repairability. We propose a low-cost, facile process for preparing superhydrophobic surfaces to address this limitation. Through a simple three-step spraying process, the rough structure was first constructed on the aluminum alloy, and upon modification by modifier, the superhydrophobic aluminum alloy surface was successfully prepared. The effect of the process parameters on wettability was experimentally studied. The results showed that this method can obtain superhydrophobic surfaces with a contact angle of 156.2° and contact angle hysteresis of 7.4° by simply adjusting the etching time and modifier concentration. In addition, it was found that the prepared surface can keep the superhydrophobic property unchanged at 180 °C, showing good thermal stability. When immersed in acetic acid and sodium hydroxide solution, the prepared surface can maintain its superhydrophobicity for about 2 days, showing good chemical stability. Besides, the surface has excellent repairability and can compensate for the short-life defects caused by poor friction resistance. This superhydrophobic surface with a simple preparation process, low cost, and excellent repairable characteristics also has excellent self-cleaning, antifogging, and antifrosting applications.