Abstract
The first diiron(iii,iv)-μ2-oxo tetracarbene complex is isolated and characterized by SC-XRD, UV/Vis, EPR, Evans' NMR and elemental analysis. CV indicates the presence of a transient high-valent diiron(iv)-μ2-oxo species. Its formation and decay is investigated via UV/Vis kinetics and NMR.
MeSH terms
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Biomimetic Materials / chemistry*
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Coordination Complexes / chemistry*
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Enzymes / metabolism*
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Iron / chemistry*
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Kinetics
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Methane / analogs & derivatives*
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Methane / chemistry
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Models, Molecular
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Molecular Conformation
Substances
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Coordination Complexes
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Enzymes
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carbene
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Iron
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Methane