Effects of Fe(III) and Cu(II) on the sorption of s-triazine herbicides on clay minerals

Abstract

The effects of Fe(III) and Cu(II) on the sorption of atrazine (AT) and prometryn (PY) on clay minerals were investigated both preloaded and in solution. For smectite, Fe(III) preloading greatly enhanced AT and PY sorption at pH 4.0 and 6.0 but diminished AT sorption at pH 8.0. Cu(II) preloading promoted AT and PY sorption under alkaline conditions but suppressed AT sorption at pH 4.0. The adverse effects were not obvious for PY. While for illite and kaolinite, Fe(III) and Cu(II) had little or promotion effects due to the lower contents of them in these two minerals. In the co-sorption studies, for smectite, AT sorption remained at pH 4.0 and increased at pH 6.0 and 8.0, while PY sorption was inhabited over the pH range of 4.0-8.0 in the presence of Fe(III). AT and PY sorption were not affected by Cu(II) except for PY at pH 8.0, in which case, the sorption was promoted. For illite and kaolinite, Fe(III) and Cu(II) generally enhanced AT and PY sorption.

Keywords: Clay minerals; S-triazine herbicides; Sorption; Transition metal ions.