Two-dimensional (2D) metal-molecule hybrid frameworks have attracted great attention due to their π-d interactions for the charge-spin-lattice coupling, promising for next-generation molecular electronics. However, a high electrical conductivity is indispensable to realize such potential. Herein, we design and assemble a conductive 2D conjugated coordination thin film through an interfacial reaction between the aqueous and organic phases. Its electronic conducting properties are derived from the π-d coupling interactions to achieve an electrical conductivity of 1.05 S/cm, while the stimulus-dependent π-d interactions induce multifunctional sensory capabilities. The Co-DABDT (DABDT = 2,5-diamino-1,4-benzenedithiol dihydrochloride) thin films demonstrate an excellent performance for sensing light, strain, temperature, and humidity, as well as robust mechanical stability. The 2D frameworks with multisensing properties for real-time static and dynamic monitoring are promising for smart wearable electronic systems.
Keywords: 2D conductive polymers; metal−organic frameworks; multiple sensory capabilities; robustness; self-assembly.