Adsorption of Reactive Red 195 from aqueous medium using Lotus (Nelumbo nucifera) leaf powder chemically modified with dimethylamine: characterization, isotherms, kinetics, thermodynamics, and mechanism assessment

Int J Phytoremediation. 2022;24(2):131-144. doi: 10.1080/15226514.2021.1929060. Epub 2021 May 31.

Abstract

In the modern era, dyes are inevitable and their surging usage leads to colossal contamination of aqueous streams, thereby threatening both the land and aquatic species. One among such dye is anionic Reactive Red 195 (RR 195), and traceable even at minute concentrations of aqueous streams, posing a severe threat to living species. Moreover, RR 195 is highly recalcitrant offering resistance to biodegradation due to the presence of an azo (-N=N-) group within its structure. Thus, there is a definite need to address the issue of eliminating RR 195 from industrial wastewater effluents. In lieu of this, the primitive objective of this study is to test the effectiveness of the natural adsorbent lotus leaf (Nelumbo nucifera) for the selective sorption of RR 195 from the aqueous stream. Although ample literature is available on the direct utilization of lotus leaf as adsorbent, yet no study was performed on the chemical modification (dimethylamine) of the aforementioned adsorbent. Hence, an attempt has been made in this direction to add a new sorbent into the adsorbents database.

Keywords: Adsorption; Lotus leaf; Reactive Red 195; isotherms; kinetics.

MeSH terms

  • Adsorption
  • Azo Compounds
  • Biodegradation, Environmental
  • Dimethylamines
  • Hydrogen-Ion Concentration
  • Kinetics
  • Lotus*
  • Naphthalenesulfonates
  • Nelumbo*
  • Plant Leaves / chemistry
  • Powders
  • Thermodynamics
  • Water Pollutants, Chemical* / analysis

Substances

  • Azo Compounds
  • Dimethylamines
  • Naphthalenesulfonates
  • Powders
  • Water Pollutants, Chemical
  • reactive red 195