Mechanisms of electron-phonon coupling unraveled in momentum and time: The case of soft phonons in TiSe2

Martin R Otto; Jan-Hendrik Pöhls; Laurent P René de Cotret; Mark J Stern; Mark Sutton; Bradley J Siwick

doi:10.1126/sciadv.abf2810

Mechanisms of electron-phonon coupling unraveled in momentum and time: The case of soft phonons in TiSe₂

Sci Adv. 2021 May 12;7(20):eabf2810. doi: 10.1126/sciadv.abf2810. Print 2021 May.

Authors

Martin R Otto¹, Jan-Hendrik Pöhls¹, Laurent P René de Cotret¹, Mark J Stern¹, Mark Sutton¹, Bradley J Siwick^{2

3}

Affiliations

¹ Department of Physics, Center for the Physics of Materials, McGill University, 3600 rue Université, Montréal, Québec H3A 2T8, Canada.
² Department of Physics, Center for the Physics of Materials, McGill University, 3600 rue Université, Montréal, Québec H3A 2T8, Canada. bradley.siwick@mcgill.ca.
³ Department of Chemistry, McGill University, 801 rue Sherbrooke Ouest, Montréal, Québec H3A 0B8, Canada.

Abstract

The complex coupling between charge carriers and phonons is responsible for diverse phenomena in condensed matter. We apply ultrafast electron diffuse scattering to unravel electron-phonon coupling phenomena in 1T-TiSe₂ in both momentum and time. We are able to distinguish effects due to the real part of the many-body bare electronic susceptibility, [Formula: see text], from those due to the electron-phonon coupling vertex, g _q , by following the response of semimetallic (normal-phase) 1T-TiSe₂ to the selective photo-doping of carriers into the electron pocket at the Fermi level. Quasi-impulsive and wave vector-specific renormalization of soft zone-boundary phonon frequencies (stiffening) is observed, followed by wave vector-independent electron-phonon equilibration. These results unravel the underlying mechanisms driving the phonon softening that is associated with the charge density wave transition at lower temperatures.

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