We present a novel and efficient approach to estimate 6D object poses of known objects in complex scenes represented by point clouds. Our approach is based on the well-known point pair feature (PPF) matching, which utilizes self-similar point pairs to compute potential matches and thereby cast votes for the object pose by a voting scheme. The main contribution of this paper is to present an improved PPF-based recognition framework, especially a new center voting strategy based on the relative geometric relationship between the object center and point pair features. Using this geometric relationship, we first generate votes to object centers resulting in vote clusters near real object centers. Then we group and aggregate these votes to generate a set of pose hypotheses. Finally, a pose verification operator is performed to filter out false positives and predict appropriate 6D poses of the target object. Our approach is also suitable to solve the multi-instance and multi-object detection tasks. Extensive experiments on a variety of challenging benchmark datasets demonstrate that the proposed algorithm is discriminative and robust towards similar-looking distractors, sensor noise, and geometrically simple shapes. The advantage of our work is further verified by comparing to the state-of-the-art approaches.