Polyvinylidene fluoride (PVDF), a material with ferroelectric characteristics, is still extremely topical for the manufacturing of transducers, and different examples, some of which have been actively commercialized since the 1980s, are reported in the literature. In this work, we present a review focused on the PVDF technology for the manufacturing of in-air ultrasonic transducers, which found application in medical robotics, sonar systems, and automation industry (e.g., proximity sensors and obstacle detection). The aim is to provide a comprehensive view on the development of such ultrasonic transducers, highlighting the constructive choices and the advantages/disadvantages in a thorough and concise way.