Facilitated Synthesis of Mg2Ni Based Composites with Attractive Hydrogen Sorption Properties

Eli Grigorova; Petar Tzvetkov; Stanislava Todorova; Pavel Markov; Tony Spassov

doi:10.3390/ma14081936

Facilitated Synthesis of Mg₂Ni Based Composites with Attractive Hydrogen Sorption Properties

Materials (Basel). 2021 Apr 13;14(8):1936. doi: 10.3390/ma14081936.

Authors

Eli Grigorova¹, Petar Tzvetkov¹, Stanislava Todorova², Pavel Markov¹, Tony Spassov²

Affiliations

¹ Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, Bl.11, Acad. G. Bonchev Str., 1113 Sofia, Bulgaria.
² Faculty of Chemistry and Pharmacy Sofia University "St. Kliment Ohridski", 1 James Bourchier Blvd., 1164 Sofia, Bulgaria.

Abstract

Composites based on Mg₂Ni with 5% activated carbon from apricot stones (ACAP) have been prepared by ball milling and subsequent annealing in hydrogen atmosphere. The purpose of the primary metal (Mg, Ni, and V) milling was to reduce the particle size and achieve a good contact between them, without forming intermetallic compounds. During hydriding/dehydriding at 300 °C the amount of the Mg₂Ni phase progressively increased, and after 10 cycles about 50% Mg₂(Ni,V) was achieved. The hydrogenation produced mainly Mg₂NiH₄, but small amounts of MgH₂ and VH_x were also detected in the powder mixture. Relatively high hydrogen storage capacity and fast hydriding/dehydriding kinetics of the Mg_2.1Ni_0.7V_0.3-5 wt.% ACAP composite were determined both from hydrogen gas phase and electrochemically.

Keywords: Mg2Ni based composite; Ni/MH battery; complex hydride Mg2NiH4; hydrogen storage.

Abstract

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