The electro-Fenton regeneration of Granular Activated Carbons: Degradation of organic contaminants and the relationship to the carbon surface

Abstract

Electrochemical regeneration of Granular Activated Carbon is an emerging treatment option to restore adsorption capacity in systems designed to remove organic contaminants from aqueous solutions. The electro-Fenton process is one such electrochemical process and it is reviewed along with other members of its family including Photoelectro-Fenton and Heterogeneous electro-Fenton and electro-Fenton like reactions, for its ability to regenerate Granular Activated Carbons contaminated with organics. The behaviour of critical operating parameter such as pH, current, catalyst concentration and initial contaminant concentration are reviewed to find optimal operating conditions. The relationship between electro-Fenton regeneration and the chemical and physical surface of the carbon is also explored. Understanding regeneration mechanisms and the optimal operating conditions enables these technologies to be used commercially and to be scaled-up and treat contaminated waters more efficiently.

Keywords: Electro-Fenton; Granular Activated Carbon; Porosity; Regeneration; Surface chemistry.