A Promising Solution for Food Waste: Preparing Activated Carbons for Phenol Removal from Water Streams

Lei Yu; David P Gamliel; Brianna Markunas; Julia A Valla

doi:10.1021/acsomega.0c06029

A Promising Solution for Food Waste: Preparing Activated Carbons for Phenol Removal from Water Streams

ACS Omega. 2021 Mar 25;6(13):8870-8883. doi: 10.1021/acsomega.0c06029. eCollection 2021 Apr 6.

Authors

Lei Yu¹, David P Gamliel², Brianna Markunas¹, Julia A Valla¹

Affiliations

¹ Department of Chemical and Biomolecular Engineering, University of Connecticut, 191 Auditorium Road, Unit 3222, Storrs, Connecticut 06269-4602, United States.
² Physical Sciences Incorporated, 20 New England Business Center Road, Andover, Massachusetts 01810, United States.

Abstract

Phenol and its derivatives are highly toxic chemicals and are widely used in various industrial applications. Therefore, the industrial wastewater streams must be treated to lower the concentration of phenol before discharge. At the same time, food waste has been a major environmental problem globally and the scientific community is eagerly seeking effective management solutions. The objective of this study was to understand the potential of utilizing food waste as a renewable and sustainable resource for the production of activated carbons for the removal of phenol from water streams. The food waste was pyrolyzed and physically activated by steam. The pyrolysis and activation conditions were optimized to obtain activated carbons with high surface area. The activated carbon with the highest surface area, 745 m² g^-1, was derived via activation at 950 °C for 1 h. A detailed characterization of the physicochemical and morphological properties of the activated carbons derived from food waste was performed and a comprehensive adsorption study was conducted to investigate the potential of using the activated carbons for phenol removal from water streams. The effects of pH, contact time, and initial concentration of phenol in water were studied and adsorption models were applied to experimental data to interpret the adsorption process. A remarkable phenol adsorption capacity of 568 mg g^-1 was achieved. The results indicated that the pseudo-second-order kinetic model was better over the pseudo-second-order kinetic model to describe the kinetics of adsorption. The intraparticle diffusion model showed multiple regions, suggesting that the intraparticle diffusion was not the sole rate-controlling step of adsorption. The Langmuir isotherm model was the best model out of Freundlich, Temkin, and Dubinin-Radushkevich models to describe the phenol adsorption on activated carbons derived from food waste. This study demonstrated that food waste could be utilized to produce activated carbon and it showed promising capacity on phenol removal.