Degradation of N-nitrosamines and 1,4-dioxane using vacuum ultraviolet irradiation (UV254+185 nm or UV172 nm)

Abstract

Advanced oxidation processes (AOPs) play a vital role in attenuating contaminants of emerging concern (CECs) during potable water reuse. AOPs are conventionally performed by irradiating with a 254-nm low-pressure (LP) mercury-vapor (Hg) ultraviolet (UV) lamp along with chemical treatment. Compared with UV-C light treatment (200-280 nm), vacuum-UV (V-UV) light treatment (100-200 nm) is advantageous in terms of hydroxyl radical generation without the requirement for chemical treatment. This study assessed the potential of V-UV (172-nm Xe₂ excimer or 185 + 254-nm LP-Hg) lamps on the destruction of two major CECs in potable water reuse, namely N-nitrosodimethylamine (NDMA) and 1,4-dioxane. Direct irradiation using UV_{254 nm} or UV_{185+254 nm} lamps achieved ≥94% removal of N-nitrosamines, including NDMA, at a UV dose of 900 mJ/cm². In contrast, the Xe₂ excimer lamp (UV_{172 nm}) was less effective for N-nitrosamine removal, achieving up to 82% removal of NDMA. The removal of 1,4-dioxane by V-UV lamps at a UV dose of 900 mJ/cm² reached 51% (UV_{172 nm}) and 28% (UV_{185+254 nm}), both of which results were superior to that obtained using a conventional UV_{254 nm} lamp (10%). The addition of hydrogen peroxide during UV_{254 nm} or UV_{185+254 nm} irradiation was found to enhance the removal of 1,4-dioxane, while UV_{172 nm} irradiation without hydrogen peroxide addition still exhibited greater efficiencies than those UV_{254 nm} lamps-based AOPs. Overall, this study demonstrated that the removal of both NDMA and 1,4-dioxane can be successfully achieved using either a UV_{254+185 nm} lamp with hydrogen peroxide or a UV_{172 nm} Xe₂ excimer lamp without hydrogen peroxide.

Keywords: AOP; CECs; Excimer; NDMA; Potable reuse; UV photolysis.