Integrated catalytic insights into methanol production: Sustainable framework for CO2 conversion

Abstract

A continuous increase in the amount of greenhouse gases (GHGs) is causing serious threats to the environment and life on the earth, and CO₂ is one of the major candidates. Reducing the excess CO₂ by converting into industrial products could be beneficial for the environment and also boost up industrial growth. In particular, the conversion of CO₂ into methanol is very beneficial as it is cheaper to produce from biomass, less inflammable, and advantageous to many industries. Application of various plants, algae, and microbial enzymes to recycle the CO₂ and using these enzymes separately along with CO₂-phillic materials and chemicals can be a sustainable solution to reduce the global carbon footprint. Materials such as MOFs, porphyrins, and nanomaterials are also used widely for CO₂ absorption and conversion into methanol. Thus, a combination of enzymes and materials which convert the CO₂ into methanol could energize the CO₂ utilization. The CO₂ to methanol conversion utilizes carbon better than the conventional syngas and the reaction yields fewer by-products. The methanol produced can further be utilized as a clean-burning fuel, in pharmaceuticals, automobiles and as a general solvent in various industries etc. This makes methanol an ideal fuel in comparison to the conventional petroleum-based ones and it is advantageous for a safer and cleaner environment. In this review article, various aspects of the circular economy with the present scenario of environmental crisis will also be considered for large-scale sustainable biorefinery of methanol production from atmospheric CO₂.

Keywords: Amine solvents; Enzymes; Greenhouse gases; Methanol; Microbes; Porphyrins.