Topological Surface State in Epitaxial Zigzag Graphene Nanoribbons

Nano Lett. 2021 Apr 14;21(7):2876-2882. doi: 10.1021/acs.nanolett.0c05013. Epub 2021 Apr 5.

Abstract

Protected and spin-polarized transport channels are the hallmark of topological insulators, coming along with an intrinsic strong spin-orbit coupling. Here we identified such corresponding chiral states in epitaxially grown zigzag graphene nanoribbons (zz-GNRs), albeit with an extremely weak spin-orbit interaction. While the bulk of the monolayer zz-GNR is fully suspended across a SiC facet, the lower edge merges into the SiC(0001) substrate and reveals a surface state at the Fermi energy, which is extended along the edge and splits in energy toward the bulk. All of the spectroscopic details are precisely described within a tight binding model incorporating a Haldane term and strain effects. The concomitant breaking of time-reversal symmetry without the application of external magnetic fields is supported by ballistic transport revealing a conduction of G = e2/h.

Keywords: STM; ballistic transport channel; tight binding; topological surface state; zigzag graphene nanoribbons.