A review of the adsorption-biological hybrid processes for the abatement of emerging pollutants: Removal efficiencies, physicochemical analysis, and economic evaluation

Laura García; Juan Carlos Leyva-Díaz; Eva Díaz; Salvador Ordóñez

doi:10.1016/j.scitotenv.2021.146554

A review of the adsorption-biological hybrid processes for the abatement of emerging pollutants: Removal efficiencies, physicochemical analysis, and economic evaluation

Sci Total Environ. 2021 Aug 1:780:146554. doi: 10.1016/j.scitotenv.2021.146554. Epub 2021 Mar 18.

Authors

Laura García¹, Juan Carlos Leyva-Díaz¹, Eva Díaz¹, Salvador Ordóñez²

Affiliations

¹ Catalysis, Reactors, and Control Research Group (CRC), Department of Chemical and Environmental Engineering, University of Oviedo, Julián Clavería s/n, 33006 Oviedo, Spain.
² Catalysis, Reactors, and Control Research Group (CRC), Department of Chemical and Environmental Engineering, University of Oviedo, Julián Clavería s/n, 33006 Oviedo, Spain. Electronic address: sordonez@uniovi.es.

PMID: 33774301
DOI: 10.1016/j.scitotenv.2021.146554

Abstract

The limited efficiency of conventional wastewater treatment plants (WWTPs) in emerging pollutants (EPs) removal encourages the development of alternative technologies for the adequate treatment of wastewater, due to its adverse effects on human health and ecosystems. The biological, physical or chemical hybrid technologies to treat EPs results interesting since they can enhance the performance of WWTPs. Among them, hybrid adsorption/biological technology could offer different possibilities that are explored in this work (PAC-MBR, PACT/GAC-CAS, BAC configurations). In this way, different variations in the adsorption process have been considered: the form of the adsorbent, the feed to the system, and the type of biological process, either conventional activated sludge (CAS), membrane bioreactor (MBR) or biofilm systems. For each combination, the removal efficiency of micropollutants, classified according to their use into pharmaceuticals, personal care products (PCPs) and other micropollutants (mainly benzotriazoles) was analysed. From reported data, it was observed a beneficial synergistic effect of dipole moment and octanol-water partition coefficient on the removal efficiency of micropollutants by adsorption/biological hybrid technology. Finally, a preliminary economic evaluation of the powdered activated carbon in a conventional activated sludge reactor (PACT), powdered activated carbon-membrane bioreactor (PAC-MBR) and biological activated carbon (BAC) hybrid systems was carried out by analysing the capital expenditure (CAPEX) of plants for capacities up to 75,000 m³d^-1. Likewise, estimations of adsorbent concentration for a hypothetical plant with a capacity of 10,000 m³d^-1 is presented. Among these hybrid configurations, PAC-MBR achieved the highest micropollutant elimination percentages; however, it presents the highest CAPEX and activated carbon requirements.

Keywords: Activated carbon; Activated sludge; Membrane bioreactor; Micropollutants; Physical-biological hybrid technologies; Wastewater.

Publication types

Review

MeSH terms

Adsorption
Bioreactors
Cost-Benefit Analysis
Ecosystem
Environmental Pollutants*
Humans
Waste Disposal, Fluid
Wastewater
Water Pollutants, Chemical* / analysis
Water Purification*

Substances

Environmental Pollutants
Waste Water
Water Pollutants, Chemical