Fe3O4 hollow nanospheres on graphene oxide as an efficient heterogeneous photo-Fenton catalyst for the advanced treatment of biotreated papermaking effluent

Abstract

This study focused on the feasibility of using Fe₃O₄/graphene oxide (FGO) nanocomposites as heterogeneous catalysts for the advanced treatment of real industrial wastewater. FGO nanocomposites with different graphene oxide (GO) ratios were synthesized by coprecipitating iron salts onto GO sheets in basic solution. The characterization of the resulting material structures and functionalities was performed using a range of analytical techniques. A low GO loading afforded a good Fe₃O₄ nanoparticle dispersibility and resulted in a higher Brunauer-Emmett-Teller surface area and pore volume. The FGO nanocomposites and pure Fe₃O₄ were used to treat papermaking wastewater in a heterogeneous photo-Fenton process. The results suggested that the nanocomposite designated FGO1 (GO loading of 25 mg) exhibits a higher photocatalytic efficiency than other FGO nanocomposites and pure Fe₃O₄. A maximum chemical oxygen demand degradation efficiency of 89.6% was achieved in 80 min with 1.5 g L^-1 FGO1 at pH 3. The degradation of different pollutants present in wastewater was evaluated with the aid of gas chromatography-mass spectrometry and 3D excitation-emission-matrix analysis. Inductively coupled plasma atomic emission spectroscopy and magnetic measurements confirmed that the FGO1 nanocomposites possess a low iron leachability and a high reusability. Thus, a comprehensive advanced treatment of real industrial wastewater using a magnetic FGO catalyst is demonstrated.

Keywords: Advanced treatment; Catalytic degradation; Graphene oxide/magnetite composite (GO/Fe3O4); Heterogeneous catalyst; Papermaking wastewater; Photo-Fenton catalyst.