Fabrication of zinc doped aluminium oxide/polysulfone mixed matrix membranes for enhanced antifouling property and heavy metal removal

Abstract

Heavy metal removal from water resources is essential for environmental protection and the production of safe drinking water. In this direction, Zinc doped Aluminium Oxide (Zn:Al₂O₃) nanoparticles were incorporated into Polysulfone (PSf) to prepare mixed matrix membranes for the efficient removal of heavy metals from water. These Zn:Al₂O₃ nanoparticles prepared by the solution combustion method have a very high surface area (261.44 m²/g) with an approximate size of 50 nm. X-ray Photoelectron Spectroscopy analysis showed that the Al and Zn were in +3 and + 2 oxidation states, respectively. Cross-sectional Scanning Electron Microscopy images revealed the finger-like morphology and porous nature of the membranes. In this study, the optimum loading amount of Zn:Al₂O₃ nanoparticles was determined. Synthesized membranes showed enhanced hydrophilicity, surface charge, and porosity, which enabled the removal of arsenic and lead with efficiencies of 87% and 98%, respectively. A study of the antifouling properties carried out at various pressures with a feed solution containing Bovine Serum Albumin (BSA) showed 98.4% of flux recovery ratio and reusability up to three continuous cycles. Moreover, this work demonstrates a rational design of novel mixed matrix membranes exhibiting characteristics of hydrophilicity, surface charge, and porosity adequate to realize the efficient removal of heavy metals.

Keywords: Anti-fouling study; Heavy metal ions; Hydrophilicity; Mixed matrix membranes.