Chitin-psyllium based aerogel for the efficient removal of crystal violet from aqueous solutions

Int J Biol Macromol. 2021 May 15:179:366-376. doi: 10.1016/j.ijbiomac.2021.02.179. Epub 2021 Feb 27.

Abstract

A new alternative aerogel was prepared from low-cost chitin and psyllium biopolymers to adsorb crystal violet (CV) dye from liquid media and possibly treat effluents containing other dyes. The aerogel was characterized by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM), which demonstrated that aerogel has a typical structure of amorphous materials and presented a randomly interconnected porous structure that resembles an open pore network. 2.5 g L-1 of aerogel was able to remove 86.00% of CV from solutions, and the natural pH of the CV solution was considered the more adequate for adsorption. The pseudo-second-order (PSO) model satisfactorily described the adsorption kinetics, and the Freundlich model was suitable to represent the adsorption equilibrium. The maximum experimental capacity achieved was 227.11 mg g-1, which indicates that aerogel is very efficient and competitive with several adsorbents. Tests using a simulated effluent showed that aerogel has excellent potential to treat real colored effluents.

Keywords: Adsorption; Aerogel; Chitin; Crystal violet; Psyllium.

MeSH terms

  • Adsorption
  • Chitin / chemistry*
  • Coloring Agents / chemistry*
  • Gentian Violet / isolation & purification*
  • Kinetics
  • Porosity
  • Psyllium / chemistry*
  • Thermodynamics
  • Water / chemistry
  • Water Pollutants, Chemical / isolation & purification*
  • Water Purification / methods*

Substances

  • Coloring Agents
  • Water Pollutants, Chemical
  • Water
  • Chitin
  • Psyllium
  • Gentian Violet