Analysis of the Influencing Factors of the Hydroxyl Radical Yield in a Hydrodynamic Cavitation Bubble of a Chitosan Solution Based on a Numerical Simulation

Xiangyu Zhang; Xinfeng Zhu; Yan Cao; Kunming Zhang; Yongchun Huang; Feng Yang; Xian'e Ren

doi:10.1021/acsomega.0c05335

Analysis of the Influencing Factors of the Hydroxyl Radical Yield in a Hydrodynamic Cavitation Bubble of a Chitosan Solution Based on a Numerical Simulation

ACS Omega. 2021 Jan 28;6(5):3736-3744. doi: 10.1021/acsomega.0c05335. eCollection 2021 Feb 9.

Authors

Xiangyu Zhang^{1

2}, Xinfeng Zhu^{1

2}, Yan Cao^{1

2}, Kunming Zhang^{1

2}, Yongchun Huang^{1

2}, Feng Yang^{1

2}, Xian'e Ren^{1

2}

Affiliations

¹ Guangxi Key Laboratory of Green Processing of Sugar Resources, Guangxi University of Science and Technology, Liuzhou 545006, Guangxi, P. R. China.
² School of Biological and Chemical Engineering, Guangxi University of Science and Technology, Liuzhou 545006, Guangxi, P. R. China.

Abstract

In this paper, the hydroxyl radical yield of a cavitation bubble and its influencing factors in the process of chitosan degradation with hydrodynamic cavitation in a single-hole orifice plate was investigated by a numerical simulation method. The hydroxyl radical yield of the cavitation bubble was calculated and analyzed by the Gilmore equation as the dynamic equation combined with the mass transfer equation, heat transfer equation, energy balance equation, and the principle of Gibbs free energy minimization. The influence of geometric parameters of the orifice plate and operating parameters on the formation of hydroxyl radicals was investigated. The results showed that the hydroxyl radicals produced at the moment of cavitation bubble collapse increased with the increase of the initial radius (R ₀), upstream inlet pressure (P ₁), downstream recovery pressure (P ₂), downstream pipe diameter (d _p), and the ratio of the orifice diameter to the pipe diameter (β). The simulation results provide a certain basis for the regulation of hydrodynamic cavitation degradation of chitosan.