Improved Redox Reaction of Lithium Polysulfides on the Interfacial Boundary of Polar CoC2 O4 as a Polysulfide Catenator for a High-Capacity Lithium-Sulfur Battery

ChemSusChem. 2021 Feb 5;14(3):757. doi: 10.1002/cssc.202100018. Epub 2021 Jan 26.

Abstract

Invited for this month's cover is the group of Jaeyoung Lee at the Gwangju Institute of Science and Technology. The cover shows how the cobalt oxalates faced on the conductive carbon can act as an electrocatalyst to facilitate the redox reaction of lithium polysulfide at the cathode interface in lithium-sulfur batteries. The facilitated electrochemical redox reaction of lithium polysulfides was proved by a series of catenation reactions formed on the interfacial boundary area. The electrochemical performance was enhanced in terms of the specific capacity and long-term cycle performance from the facilitated electrochemical activity. The Full Paper itself is available at 10.1002/cssc.202002140.