Thermal Degradation of Linalool-Chemotype Cinnamomum osmophloeum Leaf Essential Oil and Its Stabilization by Microencapsulation with β-Cyclodextrin

Molecules. 2021 Jan 14;26(2):409. doi: 10.3390/molecules26020409.

Abstract

The thermal degradation of linalool-chemotype Cinnamomum osmophloeum leaf essential oil and the stability effect of microencapsulation of leaf essential oil with β-cyclodextrin were studied. After thermal degradation of linalool-chemotype leaf essential oil, degraded compounds including β-myrcene, cis-ocimene and trans-ocimene, were formed through the dehydroxylation of linalool; and ene cyclization also occurs to linalool and its dehydroxylated products to form the compounds such as limonene, terpinolene and α-terpinene. The optimal microencapsulation conditions of leaf essential oil microcapsules were at a leaf essential oil to the β-cyclodextrin ratio of 15:85 and with a solvent ratio (ethanol to water) of 1:5. The maximum yield of leaf essential oil microencapsulated with β-cyclodextrin was 96.5%. According to results from the accelerated dry-heat aging test, β-cyclodextrin was fairly stable at 105 °C, and microencapsulation with β-cyclodextrin can efficiently slow down the emission of linalool-chemotype C. osmophloeum leaf essential oil.

Keywords: Cinnamomum osmophloeum; linalool; microencapsulation; β-cyclodextrin.

MeSH terms

  • Acyclic Monoterpenes / chemistry*
  • Capsules
  • Cinnamomum / chemistry*
  • Drug Stability
  • Hot Temperature
  • Oils, Volatile / chemistry*
  • Plant Leaves / chemistry*
  • Plant Oils / chemistry*
  • beta-Cyclodextrins / chemistry*

Substances

  • Acyclic Monoterpenes
  • Capsules
  • Oils, Volatile
  • Plant Oils
  • beta-Cyclodextrins
  • linalool