Recent developments in using the molecular decay dating method: a review

Ann N Y Acad Sci. 2021 Jun;1493(1):29-40. doi: 10.1111/nyas.14560. Epub 2021 Jan 14.

Abstract

The dating of organic findings is a fundamental task for many scientific fields. Radiocarbon dating is currently the most commonly used method. For wood, dendrochronology is another state-of-the-art method. Both methods suffer from systematic restrictions, leading to samples that have not yet been able to be dated. Molecular changes over time are reported for many materials under different preservation conditions. Many of them are intrinsically monotonous. These monotonous molecular decay (MD) patterns can be understood as clocks that start at the time when a given molecule was formed. Factors that influence these clocks include input material composition and preservation conditions. Different wood species, degrees of pyrolysis, and pretreatments lead to different prediction models. Preservation conditions might change the speed of a given clock and lead to different prediction models. Currently published models for predicting the age of wood, paper, and parchment depend on infrared spectroscopy. In contrast to radiocarbon dating, dating via MD does not comprise a single methodology. Some clocks may deliver less precise results than the others. Ultimately, developing a completely different, new dating strategy-such as MD dating-will help to bring to light a treasure trove of information hidden in the darkness of organic findings.

Keywords: FTIR spectroscopy; archaeometry; organic matter; taphonomy.

Publication types

  • Historical Article
  • Review

MeSH terms

  • Amber / chemistry
  • Animals
  • Archaeology / methods*
  • Archaeology / trends
  • Bone and Bones / chemistry
  • Charcoal / chemistry
  • Hair / chemistry
  • History, Ancient
  • Humans
  • Organic Chemicals / analysis*
  • Organic Chemicals / chemistry
  • Paper
  • Plant Bark / chemistry
  • Preservation, Biological
  • Radiometric Dating / methods*
  • Radiometric Dating / trends
  • Skin / chemistry
  • Spectroscopy, Fourier Transform Infrared
  • Time Factors
  • Wood / chemistry

Substances

  • Amber
  • Organic Chemicals
  • Charcoal