Iridium and Ruthenium Modified Polyaniline Polymer Leads to Nanostructured Electrocatalysts with High Performance Regarding Water Splitting

Razik Djara; Marie-Agnès Lacour; Abdelhafid Merzouki; Julien Cambedouzou; David Cornu; Sophie Tingry; Yaovi Holade

doi:10.3390/polym13020190

Iridium and Ruthenium Modified Polyaniline Polymer Leads to Nanostructured Electrocatalysts with High Performance Regarding Water Splitting

Polymers (Basel). 2021 Jan 7;13(2):190. doi: 10.3390/polym13020190.

Authors

Razik Djara^{1

2}, Marie-Agnès Lacour³, Abdelhafid Merzouki¹, Julien Cambedouzou², David Cornu², Sophie Tingry², Yaovi Holade²

Affiliations

¹ Laboratoire de Physico-Chimie des Hauts Polymères (LPCHP), Université Ferhat Abbas, Sétif 19000, Algeria.
² Institut Européen des Membranes, IEM UMR 5635, University of Montpellier, ENSCM, CNRS, 34090 Montpellier, France.
³ ChemLab, CEDEX 5, 34296 Montpellier, France.

Abstract

The breakthrough in water electrolysis technology for the sustainable production of H₂, considered as a future fuel, is currently hampered by the development of tough electrocatalytic materials. We report a new strategy of fabricating conducting polymer-derived nanostructured materials to accelerate the electrocatalytic hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and water splitting. Extended physical (XRD, scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX)) and electrochemical (cyclic voltammetry (CV), linear sweep voltammetry (LSV), electrochemical impedance spectroscopy (EIS)) methods were merged to precisely characterize the as-synthesized iridium and ruthenium modified polyaniline (PANI) materials and interrogate their efficiency. The presence of Ir(+III) cations during polymerization leads to the formation of Ir metal nanoparticles, while Ru(+III) induces the formation of RuO₂ oxide nanoparticles by thermal treatment; they are therefore methods for the on-demand production of oxide or metal nanostructured electrocatalysts. The findings from using 0.5 M H₂SO₄ highlight an ultrafast electrochemical kinetic of the material PANI-Ir for HER (36 - 0 = 36 mV overpotential to reach 10 mA cm^-2 at 21 mV dec^-1), and of PANI-Ru for OER (1.47 - 1.23 = 240 mV overpotential to reach 10 mA cm^-2 at 47 mV dec^-1), resulting in an efficient water splitting exactly at its thermoneutral cell voltage of 1.45 V, and satisfactory durability (96 h).

Keywords: conducting polymer; electrocatalysis; hydrogen evolution reaction; oxygen evolution reaction; polyaniline; water splitting.