Multiple Anti-Counterfeiting Composite Film Based on Cholesteric Liquid Crystal and QD Materials

ACS Appl Mater Interfaces. 2021 Jan 13;13(1):1424-1430. doi: 10.1021/acsami.0c18132. Epub 2021 Jan 5.

Abstract

A composite film with multiple anti-counterfeiting features was demonstrated by superposing quantum dots (QDs) polymer matrix (film A) and cholesteric liquid crystal film (film B) together. The first-line and second-line anti-counterfeiting characteristics were successfully implemented by employing thermochromic, angular photochromic, and circularly polarized discoloration of film B, respectively. By initiatively utilizing the different relative positions between the fluorescence emission peak (λem) of film A and the central selective reflection wavelength (λm) of film B at different temperatures, which resulted in changes in the fluorescence spectra or the different presence of latent patterns, the most important third-line anti-counterfeiting feature was successfully achieved.

Keywords: cholesteric phase; liquid crystals; multiple anti-counterfeiting; quantum dots; side-chain liquid crystal polymers.