Nonlinear and thermo-optical characterisation of bare imidazolium ionic liquids

Vinícius C Ferreira; Graciane Marin; Jairton Dupont; Ricardo R B Correia

doi:10.1088/1361-648X/abcdaf

Nonlinear and thermo-optical characterisation of bare imidazolium ionic liquids

J Phys Condens Matter. 2020 Dec 16;33(9). doi: 10.1088/1361-648X/abcdaf.

Authors

Vinícius C Ferreira¹, Graciane Marin², Jairton Dupont², Ricardo R B Correia¹

Affiliations

¹ OPTMA - Optics, Photonics and Materials Group, Institute of Physics, Universidade Federal do Rio Grande do Sul, Porto Alegre, Brazil.
² LAMOCA - Laboratory of Molecular Catalysis, Institute of Chemistry, Universidade Federal do Rio Grande do Sul, Porto Alegre, Brazil.

PMID: 33331295
DOI: 10.1088/1361-648X/abcdaf

Abstract

Nonlinear optical (NLO) and thermo-optical properties of two pure ionic liquids, BMIOMe.NTf₂and BMIOMe.N(CN)₂, were examined in this study. This was the first nonlinear refractive index determination of a pristine ionic liquid by a standard self-refraction experiment. The NLO characterisations were performed using Z-scan and EZ-scan techniques in the thermally managed approach, with a mode-locked femtosecond laser source. Thermal properties were analysed concomitantly, and the thermo-optical coefficient, thermal characteristic time, and lens strength were characterised. These results define the parameters to be adopted in the method of nanoparticles formation by laser ablation in an ionic liquid solution and indicate that BMIOMe.NTf₂is a prominent material to be engineered for photonics applications.

Keywords: EZ-scan; Z-scan; ionic liquid; nonlinear characterization.