Green Composites Based on Unsaturated Polyester Resin from Recycled Poly(Ethylene Terephthalate) with Wood Flour as Filler-Synthesis, Characterization and Aging Effect

Polymers (Basel). 2020 Dec 11;12(12):2966. doi: 10.3390/polym12122966.

Abstract

The paper investigates the synthesis of green composites and their properties before and after the laboratory accelerated aging tests. Materials were made of unsaturated polyester resins (UPRs) based on recycled poly(ethylene terephthalate) (PET) and wood flour (WF). The effect of dibenzylideneacetone (dba) addition on mechanical and thermomechanical properties was also determined. Green composites were obtained using environment friendly polymeric cobalt as an accelerator. Before and after exposition to the xenon lamp radiation, the UPRs physically modified by WF were characterized only by a greater flexural modulus compared with the analogous composites based on the pure resin. Addition of dba caused the increase of flexural modulus, flexural strength, strain at break and mechanical loss factor compared to the non-modified material. After aging only the last mentioned parameter took on lower values compared to the pure resin analogues.

Keywords: accelerated aging test; dibenzylideneacetone; green composites; recycled PET; unsaturated polyester resins; wood flour.