In this study, hydrothermal liquefaction of household waste was performed to produce valuable liquid hydrocarbons with aqueous phase as by-product. Photocatalytic reforming of aqueous phase was carried out for hydrogen production. Liquefaction of 15 g waste at temperature of 320 °C and solvent to biomass ratio of 13.33 mL/g produced bio-oil of 32.4 wt% and hydrogen 21 wt% in gas product. Hydrogen production from aqueous phase was studied in presence of various concentrations of activated carbon doped Fe/TiO2 catalyst (0.2-1 wt%). Hydrogen yield was 32 wt% when 0.6 wt% of catalyst was used to reform aqueous phase. To ease of operation in economical manner the reusability study of the catalyst was evaluated and it was found to be active for three consecutive cycles. As outcome of this study, household waste can serve for a whooping amount of hydrogen (53 wt%) production via liquefaction and photocatalytic reforming process.
Keywords: Bio-oil; Hydrogen; Hydrothermal liquefaction; Photocatalytic reforming; Waste.
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