Double-side microcantilevers as a key to understand the adsorption mechanisms and kinetics of chemical warfare agents on vertically-aligned TiO2 nanotubes

Guillaume Thomas; Denis Spitzer

doi:10.1016/j.jhazmat.2020.124672

Double-side microcantilevers as a key to understand the adsorption mechanisms and kinetics of chemical warfare agents on vertically-aligned TiO₂ nanotubes

J Hazard Mater. 2021 Mar 15:406:124672. doi: 10.1016/j.jhazmat.2020.124672. Epub 2020 Nov 28.

Authors

Guillaume Thomas¹, Denis Spitzer²

Affiliations

¹ Laboratoire Nanomatériaux pour les Systèmes Sous Sollicitations Extrêmes (NS3E), UMR 3208 ISL/CNRS/UNISTRA, French-German Research Institute of Saint-Louis, 5 rue du Général Cassagnou, 68300 Saint-Louis, France.
² Laboratoire Nanomatériaux pour les Systèmes Sous Sollicitations Extrêmes (NS3E), UMR 3208 ISL/CNRS/UNISTRA, French-German Research Institute of Saint-Louis, 5 rue du Général Cassagnou, 68300 Saint-Louis, France. Electronic address: denis.spitzer@isl.eu.

PMID: 33310337
DOI: 10.1016/j.jhazmat.2020.124672

Abstract

Microgravimetric sensor platforms with physico- or chemo-selective interfaces offer promising sensing properties. They are widely used to detect chemical warfare agents (CWAs). However, a comprehensive insight into adsorption mechanisms and interactions between low concentrations of these adsorbates and low-mass adsorbents is still lacking. In this study, we report a complete and detailed analytical method to model the adsorption processes of low traces of vapor-phase DiMethyl MethylPhosphonate (DMMP), a conventional simulant of CWAs, on a double-side nanostructured microcantilever coated with vertically-aligned titanium dioxide nanotubes (TiO₂-NTs). We find that the geometrical configuration of NTs plays an important role in the diffusion regimes of molecules during the adsorption. This study shines light on the adsorption and kinetic mechanisms of low-traces DMMP offering opportunities to have a better insight of the adsorption of CWAs on complex nanostructures and to improve microcantilever sensors.

Keywords: Kinetic and adsorption mechanisms; Nanostructured microcantilever sensor; Non-linear regression and error function; Organophosphorous compounds; Two and three-parameters isotherms.