Development of red apple pomace extract/chitosan-based films reinforced by TiO2 nanoparticles as a multifunctional packaging material

Abstract

A chitosan-based (CS) film was developed with nanosized TiO₂ and red apple pomace extract (APE). The intermolecular interactions of CS, TiO₂ and APE were evaluated by Fourier transform infrared spectroscopy, scanning electron microscopy and X-ray diffraction. TiO₂ nanoparticles remarkably improved the water vapor and UV-Vis light barrier properties, mechanical strength and thermal stability of CS-APE films. The strong antioxidant abilities of CS-APE and CS-TiO₂-APE films were characterized. Nano-TiO₂ and APE showed a synergistic enhancement of the antimicrobial activity in CS matrix. The addition of TiO₂ nano-particles into CS-APE films resulted the sensitive color variations, which applied successfully as an indicator to monitor the freshness of salmon fillets. Consequently, the development of CS-APE-TiO₂ film provides a new solution to convert rad apple pomace to an active and multifunctional food packaging material with considerable mechanical, antibacterial, antioxidant and pH-responsive color-changing properties.

Keywords: Apple pomace; Chitosan; Processing waste; TiO(2) nanoparticles; pH-sensitive film.