Supramolecular solvent-based micro-extraction of pesticides in food and environmental samples

Abstract

Supramolecular solvent-based micro-extraction is a very important green technique for the isolation and pre-concentration of pesticide residues in food and environmental samples prior to their chromatographic analysis. The attractive features of supramolecular solvent-based micro-extraction include its simplicity, high pre-concentration factor, fastness, accuracy, low cost, less consumption of chemical reagents and environmental friendliness. The supramolecular solvent is generated from a ternary mixture of amphiphiles, water and a water miscible dispersion and coacervating solvent. Tehydrofuran is one of the solvents commonly used as both a dispersion solvent and a coacervating agent. This paper gives a recent comprehensive review on the application of alkanols as amphiphiles during supramolecular solvent-based micro-extraction of pesticide residues in food and environmental samples. Other researchers used long chain fatty acids as amphiphiles during pesticide analysis in food and environmental samples using supramolecular solvent-based micro-extraction, and this is discussed in this paper. The incorporation of ferrofluids in supramolecular solvents enables phase separation using a magnet instead of the time-consuming centrifugation technique. This paper also gives a detailed review of the application of ferrofluid-based supramolecular solvent micro-extraction of pesticide residues in food and environmental samples.

Keywords: Amphiphile; Coacervaton; Micro-extraction; Pesticides; Self-assembly; Supramolecular solvents.