The development of mechanochromic or self-reporting polymers that can indicate damage or fatigue of materials with an optical signal has become of paramount interest to ensure the reliability of the materials and prevent catastrophic failure. This technology can potentially find usefulness for various applications, including in situ monitoring of mechanical events and structural health monitoring systems. An emerging and versatile approach to achieve mechanochromic properties relies on the encapsulation of dye solutions that can be released and activated (chemically or physically) when the walls of the capsules are mechanically damaged. While the mechanochromic effect can be achieved with different types of dyes and operating principles, this framework can also be designed with encapsulating-containers of different shapes and shell materials, such as microcapsules, hollow glass fibers, vascular networks, and micelles, making this concept applicable to a broad range of polymer matrices. An overview of the different encapsulation approaches that have been employed to prepare mechanochromic polymers is given, with a focus on the containers used for this purpose. A brief description of the containers' preparation is provided, and their associated chromic operating principles and progress in their designs are reviewed.
Keywords: hollow fibers; mechanochromic polymers; micelles; microcapsules; vascular networks.
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