Influences of the Thomson Effect on the Performance of a Thermoelectric Generator-Driven Thermoelectric Heat Pump Combined Device

Entropy (Basel). 2018 Jan 5;20(1):29. doi: 10.3390/e20010029.

Abstract

A thermodynamic model of a thermoelectric generator-driven thermoelectric heat pump (TEG-TEH) combined device is established considering the Thomson effect and the temperature dependence of the thermoelectric properties based on non-equilibrium thermodynamics. Energy analysis and exergy analysis are performed. New expressions for heating load, maximum working temperature difference, coefficient of performance (COP), and exergy efficiency are obtained. The performance is analyzed and optimized using numerical calculations. The general performance, optimal performance, optimum variables, optimal performance ranges, and optimum variable ranges are obtained. The results show that the Thomson effect decreases the general performance and optimal performance, and narrows the optimal operating ranges and optimum variable ranges. Considering the Thomson effect, more thermoelectric elements should be allocated to the thermoelectric generator when designing the devices. The optimum design variables for the maximum exergy efficiency are different from those for the maximum COP. The results can provide more scientific guidelines for designing TEG-TEH devices.

Keywords: Thomson effect; combined thermoelectric device; exergy analysis; non-equilibrium thermodynamics; performance analysis and optimization; temperature dependence; thermoelectric generator; thermoelectric heat pump.