Ionic liquids as environmental hazards - Crucial data in view of future PBT and PMT assessment

Abstract

Ionic liquids (ILs) constitute a large group of chemical compounds. They have gained much attention among scientists and industry due to their unique properties. Due to the fact that ILs are purely ionic compounds, there is the possibility to design an enormous number of cation and anion combinations, making them designer solvents. Thus it also creates the possibility of producing more environmentally benign solvents. However, significant drawbacks related mainly to their toxicity and persistence have already been noticed. Furthermore the interest in these compounds is constantly growing and their impact on the environment should be defined. More and more ILs are produced or imported in the amount higher than 10 tonnes per year and the group of ILs registered in REACH is still expanding. Thus for an increasing number of compounds, it will be necessary to perform a PBT and PMT assessment using the criteria described in REACH. Therefore the data collected in this work thoroughly sort out the information on the toxicity, bioconcentration/bioaccumulation, biodegradation and mobility of ILs in the context of PBT and PMT assessment.

Keywords: Bioaccumulation; Persistence; REACH; Sorption; Toxicity.