Microwave-assisted catalytic pyrolysis of waste printed circuit boards, and migration and distribution of bromine

Abstract

Microwave-assisted pyrolysis (MAP) of waste printed circuit boards (WPCB) was performed to investigate the characteristics of pyrolysis product and Br fixation. Pyrolysis conversion increased with increasing temperature, reaching 93.3 % at 650 °C. However, increasing heating time did not exhibit remarkable influence on pyrolysis conversion. At 350 °C, phenols were main compounds in the oil accounting for 91.15 %. As the temperature increased to 650 °C, polycyclic aromatic hydrocarbons and monocyclic aromatic hydrocarbons (except phenols) increased to 20.55 % and 19.03 %, respectively. Meanwhile, the total content of CO₂, CO, CH₄ and H₂ in the non-condensable gases increased significantly. Addition of ZSM-5 and kaolin promoted the recombination reaction of pyrolysis products, increased the relative percentage of monocyclic aromatic hydrocarbons (except phenols) and C₁₁-C₂₀ compounds in the oil, and reduced non-condensable gases. The oxygen bomb-ion chromatography was used to evaluate the Br content of pyrolysis residues. Higher pyrolysis temperature enhanced transfer of Br to pyrolysis gas. K₂CO₃, Na₂CO₃ and NaOH reacted with hydrogen bromide to generate KBr and NaBr, which significantly improved the Br fixation efficiency of pyrolysis residues (i.e. from 29.11%-99.80%, 96.39 % and 86.69 %, respectively) and reduced Br content in pyrolysis gas.

Keywords: Bromine retention; Catalytic pyrolysis; Microwave-assisted pyrolysis; Waste printed circuit board.