Influence of Brønsted and Lewis acidity of the modified Al-MCM-41 solid acid on cellulose conversion and 5-hydroxylmethylfurfuran selectivity

Abstract

The modified Al-MCM-41 solid acids with turning Si/Al molar ratio were successfully fabricated through a hydrothermal route and utilized as a suitable catalyst in the cellulose conversion into 5-hydroxylmethylfurfural (5-HMF). The crystal structure, composition, morphologies and porosity of as-synthesized acids were characterized by XRD, FT-IR, N₂ adsorption-desorption, TEM and EDS. The ²⁷Al MAS NMR and ²⁹Si-MAS NMR results revealed the existence of both Al framework and Al extra framework. Besides, the existence of medium-weak and strong acid sites, according to Brønsted and Lewis acidity, in Al-MCM-41 acids was confirmed by NH₃-TPD and FTIR-pyridine adsorption. The 30Al-MCM-41 solid acid (Si/Al molar ratio = 30) exhibited excellent activity with the highest 5-HMF yield of 40.56% compared to other samples. We also discovered that 5-HMF production, as well as cellulose conversion, strongly depended on the total acid, strong/medium-weak acid ratio, as well as Brønsted/Lewis acid ratio. Therefore, these parameters have been considered as essential factors for the design of solid acid for 5-HMF production.

Keywords: 5-HMF yield; Al-MCM-41 soild acid; Brønsted and Lewis acidity; Cellulose conversion.