Controlled-Potential-Based Electrochemical Sulfide Sensors: A Review

Chem Rec. 2021 Jan;21(1):204-238. doi: 10.1002/tcr.202000115. Epub 2020 Nov 17.

Abstract

Due to their potential applications in industry and potent toxicity to the environment, sulfides and their detection have attracted the attention of researchers. To date, a large number of controlled-potential techniques for electrochemical sulfide sensors have been developed, thanks to their simplicity, reasonable limit of detection (LOD), and good selectivity. Different researchers have applied different strategies for developing selective and sensitive sulfide sensors. However, there has been no systematic review on controlled-potential techniques for sulfide sensing. In light of this absence, the main aim of this review article is to summarize various strategies for detecting sulfide in different media. The efficiencies of the developed sulfide sensors for detecting sulfide in its various forms are determined, and the essential parameters, including sensing strategies, working electrodes, detection media, pH, LOD, sensitivity, and linear detection range, are emphasized in particular. Future research in this area is also recommended. It is expected that this review will act as a basis for further research on the fabrication of sulfide sensors for practical applications.

Keywords: direct electro-oxidation; electrochemical sulfide sensors; electron-meditator-based oxidation; sensing strategies; stripping.

Publication types

  • Review