This article demonstrates the one-pot reaction, an efficient and environmentally friendly organic synthesis method, utilized to prepare the silanized silica-encapsulated calcium carbonate@natural rubber composites (SSC@NR), following first mixing the calcium carbonate (CaCO3) solution, silica (SiO2) sol solution and a small amount of Si-69 solution, to modify the surface of CaCO3 particles, and then wet mixing with natural rubber latex. The obtained silanized silica-encapsulated calcium carbonate (SSC) particles were tested by TGA, FTIR and XRD, to substantiate the effect of surface modification. Moreover, the effects of the amount of SSC on the Mooney viscosity, curing characteristics, physical and mechanical properties and dynamic mechanical properties of the SSC@NR were investigated. The results show that the surface of modified CaCO3 is effectively coated with SiO2 particles by means of physical and chemical combination, to achieve the effect of surface coating. When the optimum amount of SSC filler is 40 phr, the SSC can form better physical adsorption and chemical combination with the NR molecular chains and can be evenly dispersed in the rubber matrix, resulting in the conspicuous improvement of physical and mechanical properties, such as the tensile strength, tear strength, elongation at break and abrasion resistance. Meanwhile, the compound with SSC has preferable processability and dynamic mechanical properties.
Keywords: calcium carbonate; silica; surface modification; wet mixing.