Detection of Pb(II): Au Nanoparticle Incorporated CuBTC MOFs

Gajanan A Bodkhe; Bhavna S Hedau; Megha A Deshmukh; Harshada K Patil; Sumedh M Shirsat; Devdatta M Phase; Krishan K Pandey; Mahendra D Shirsat

doi:10.3389/fchem.2020.00803

Detection of Pb(II): Au Nanoparticle Incorporated CuBTC MOFs

Front Chem. 2020 Oct 15:8:803. doi: 10.3389/fchem.2020.00803. eCollection 2020.

Authors

Gajanan A Bodkhe¹, Bhavna S Hedau¹, Megha A Deshmukh¹, Harshada K Patil¹, Sumedh M Shirsat², Devdatta M Phase³, Krishan K Pandey⁴, Mahendra D Shirsat¹

Affiliations

¹ RUSA Center for Advanced Sensor Technology, Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, India.
² Department of Electronics and Telecommunication Engineering, Jawaharlal Nehru Engineering College, Aurangabad, India.
³ UGC-DAE Consortium for Scientific Research, University Campus, Indore, India.
⁴ High Pressure and Synchrotron Radiation Physics Division, Bhabha Atomic Research Center, Mumbai, India.

Abstract

In the present investigation, copper benzene tricarboxylate metal organic frameworks (CuBTC MOF) and Au nanoparticle incorporated CuBTC MOF (Au@CuBTC) were synthesized by the conventional solvothermal method in a round bottom flask at 105°C and kept in an oil bath. The synthesized CuBTC MOF and Au@CuBTC MOFs were characterized by structure using X-ray diffraction (XRD) spectroscopic methods including Fourier Transform Infrared spectroscopy, Raman Spectroscopy, X-ray Photoelectron Spectroscopy (XPS), and Energy dispersive spectroscopy (EDS). We also characterized them using morphological techniques such as Field emission scanning electron microscopy (FE-SEM), and electrochemical approaches that included cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). We examined thermal stability by thermogravimetric analysis (TG/DTA) and N₂ adsorption-desorption isotherm by Brunauer-Emmett-Teller (BET) surface area method. Both materials were tested for the detection of lead (II) ions in aqueous media. Au nanoparticle incorporated CuBTC MOF showed great affinity and selectivity toward Pb²⁺ ions and achieved a lower detection limit (LOD) of 1 nM/L by differential pulse voltammetry (DPV) technique, which is far below than MCL for Pb²⁺ ions (0.03 μM/L) suggested by the United States (U.S.) Environmental Protection Agency (EPA) drinking water regulations.

Keywords: CuBTC MOF; differential pulse voltammetry (DPV); electrochemical sensor; gold nanoparticles; metal organic frameworks.