This work presented facile fabrication of carbon nitride (CN)/zinc titanate (ZT) heterojunction by one-step ball milling process for visible light-induced photocatalytic degradation. The phase structures, morphologies, functional groups, and optical properties of the prepared materials were systematically characterized by XRD, FTIR, UV-Vis DRS, and SEM techniques. The ball milling for 10 min significantly improved visible light absorption properties; the as-synthesized ZT/CN catalyst (2.8 eV) showed lower band gap energy than bare ZT (3.2 eV). This result revealed a successful incorporation. The photocatalytic activities of the heterostructure catalysts (ZT/CN) evaluated by degrading tetracycline under visible light irradiation and highest TC removal rate were obtained as 0.0193 min-1 for ZT/CN/5, which was 6.2 times higher than that of bare CN. The most efficient photocatalyst (ZT/CN/5) could be performed three times without any loss of phase. In addition, the heterostructure catalyst was found as promising candidate for efficient photocatalytic degradation of other antibiotics and dye components.
Keywords: Ball-milling; Carbon nitride; Photocatalysis; Tetracycline; Visible light; Zinc titanate.