Three-dimensional (3D) printing is a very flexible process to design various objects of original shapes. Previous works highlighted the preparation of new multimaterials composed of an original sandwich structure made of the ethylene vinyl acetate copolymer containing 30 wt % of aluminum trihydroxide in which a hydrogel phase made of agar and vermiculite was incorporated. This original material revealed an extremely low heat release rate (HRR) (with a reduction of 86 and 64% with regard to the peak of the HRR and total heat release, respectively, when compared to the same sample without hydrogel filling) during its heat exposure at 50 kW/m2 according to the mass loss cone calorimetry test. However, the time to ignition (TTI) of this material was not improved. This work consequently focuses on delaying the time to ignition of this hydrogel sandwich 3D-printed multimaterial. Solution consists in depositing by pulsed DC magnetron sputtering a low-emissivity thin coating on the exposed skin surface. This coating reflects most of the infrared rays responsible for heat absorption and thus delays the ignition of the underlying material. The thermal resistance performances of this coated sandwich 3D-printed multimaterial were evaluated, and a mechanism of action was proposed to explain the dramatic enhancement of the properties.