The current study presents the oxidative potential (OP) along with a wide range of chemical speciation of particulate matter with an aerodynamic diameter less than 10 μm (PM10) at five sites representing different environments in Ahmedabad, a big city in western India. On an average, PM10 concentrations were 116 ± 36, 228 ± 43, 133 ± 29, 101 ± 21, and 70 ± 20 μg m-3; volume-normalized OP (OPV) were 2.51 ± 0.71, 5.62 ± 0.68, 2.69 ± 0.76, 2.14 ± 0.41, and 1.55 ± 0.51 nmol DTT min-1 m-3; and mass-normalized OP (OPM) were 22 ± 3, 25 ± 5, 21 ± 6, 21 ± 2, and 22 ± 3 pmol DTT min-1 μg-1 over Bapunagar (backward residential area), Narol (industrial), Paldi (bus transport hub), Income Tax (huge running traffic) and Science City (posh residential area), respectively. Overall, OPV showed a significant linear correlation with PM10, whereas OPM showed near uniformity with increasing PM10. Although the OPM values were similar, the site-to-site variability in PM10 concentration reflects the corresponding health risks associated with PM10 exposure for the people living in these areas. Further, a noticeable temporal variation in OPM at Narol and Paldi suggests that species with diverse OPM contributed to PM10 on different days. A strong linear relationship between the ratio of OPV to the mass concentration of organic carbon (OPOC) and the ratio of m/z 43 signal to total water-soluble organic aerosols (WSOA) signals (f43) suggests that the fossil-fuel combustion derived WSOA have higher OP. Furthermore, the relationships of OP with water-soluble trace metals and brown carbon are also investigated and discussed in this paper. Nitrogenous organic compounds particularly emitted from the traffic-related sources in Paldi and Income Tax have higher OPOC than those emitted from other sources over Bapunagar, Narol, and Science City.
Keywords: DTT; Nitrogenous organic aerosols; Reactive oxygen species; Urban; Water-soluble trace metals.
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