Applications of Low-Melting-Point Metals in Rechargeable Metal Batteries

Chemistry. 2021 Apr 12;27(21):6407-6421. doi: 10.1002/chem.202003921. Epub 2021 Feb 16.

Abstract

Low-melting-point (LMP) metals represent an interesting family of electrode materials owing to their high ionic conductivity, good ductility or fluidity, low hardness and/or superior alloying capability, all of which are crucial characteristics to address battery challenges such as interfacial incompatibility, electrode pulverization, and dendrite growth. This minireview summarizes recent research progress of typical LMP metals including In, Ga, Hg, and their alloys in rechargeable metal batteries. Emphasis is placed on mainstream electrochemical storage devices of Li, Na, and K batteries as well as the representative multi-valent metal batteries. The fundamental correlations between unique physiochemical properties of LMP metals and the battery performance are highlighted. In addition, this article also provides insights into future development and potential directions of LMP metals/alloys for practical applications.

Keywords: alloy; anodes; gallium; indium; mercury; rechargeable batteries.

Publication types

  • Review