Ultrasound-assisted catalytic reduction of Cr(VI) by an acid mine drainage based nZVI coupling with FeS2 system from aqueous solutions: Performance and mechanism

Abstract

Nowadays, nanoscale zero valent iron (nZVI) has been extensively applied for the decontamination of various pollutants, but passivation of nZVI severely affects its reactivity in use. In this study, ultrasound (US)-assisted catalytic reduction of Cr(VI) by an acid mine drainage based nZVI (AMD-nZVI) coupling with FeS₂ system was systematically examined. Results show that the presence of FeS₂ and US induced a synergistic enhancement of Cr(VI) removal by AMD-nZVI. Nearly 98% of Cr(VI) removal was achieved by AMD-nZVI/FeS₂/US process within 60 min under optimal reaction conditions. Several coexisting substances with lower concentration including Pb(II), Ni(II), bisphenol A (BPA) and 2,4-diclorophenol (2,4-DCP) could be effectively removed in simultaneous manner with Cr(VI) removal. The inhibitory order of water matrix species on Cr(VI) removal was NO₃^- > PO₄^3- > HCO₃^- > Ca²⁺ > Mg²⁺ > Cl^-, and a serious suppression effect was induced by humic acid (HA). Addition of ethylene diamine tetra-acetic acid (EDTA) and citric acid (CA) could enhance Cr(VI) removal rate. An enhanced reaction mechanism was proposed, which involved the regeneration of more Fe²⁺ and H⁺ by AMD-nZVI/FeS₂/US process, leading to the reduction of Cr(VI) by AMD-nZVI and FeS₂ into Cr(III) species inculding Cr₂O₃ and Cr(OH)₃. This study well demonstrates that AMD-nZVI/FeS₂/US process is considered as a potential candidate for the remediation of Cr(VI) in real wasterwater.

Keywords: Cr(VI); Enhanced removal; FeS(2); Waste utilization; nZVI.