Imidazolium-Based Ionic Liquids as Clay Swelling Inhibitors: Mechanism, Performance Evaluation, and Effect of Different Anions

Rizwan Ahmed Khan; Mobeen Murtaza; Abdulazeez Abdulraheem; Muhammad Shahzad Kamal; Mohamed Mahmoud

doi:10.1021/acsomega.0c03560

Imidazolium-Based Ionic Liquids as Clay Swelling Inhibitors: Mechanism, Performance Evaluation, and Effect of Different Anions

ACS Omega. 2020 Oct 6;5(41):26682-26696. doi: 10.1021/acsomega.0c03560. eCollection 2020 Oct 20.

Authors

Rizwan Ahmed Khan¹, Mobeen Murtaza¹, Abdulazeez Abdulraheem¹, Muhammad Shahzad Kamal², Mohamed Mahmoud¹

Affiliations

¹ Petroleum Engineering Department, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia.
² Center for Integrative Petroleum Research, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia.

Abstract

Clay swelling is one of the challenges faced by the oil industry. Water-based drilling fluids (WBDF) are commonly used in drilling operations. The selection of WBDF depends on its performance to improve rheology, hydration properties, and fluid loss control. However, WBDF may result in clay swelling in shale formations during drilling. In this work, the impact of imidazolium-based ionic liquids on the clay swelling was investigated. The studied ionic liquids have a common cation group, 1-allyl-3-methyllimidozium, but differ in anions (bromide, iodide, chloride, and dicyanamide). The inhibition behavior of ionic liquids was assessed by linear swell test, inhibition test, capillary suction test, rheology, filtration, contact angle measurement, scanning electron microscopy, and X-ray diffraction (XRD). It was observed that the ionic liquids with different anions reduced the clay swelling. Ionic liquids having a dicyanamide anion showed slightly better swelling inhibition performance compared to other inhibitors. Scanning electron microscopy images showed the water tendency to damage the clay structure, displaying asymmetrical cavities and sharp edges. Nevertheless, the addition of an ionic liquid to sodium bentonite (clay) exhibited fewer cavities and a smooth and dense surface. XRD results showed the increase in d-spacing, demonstrating the intercalation of ionic liquids in interlayers of clay. The results showed that the clay swelling does not strongly depend on the type of anion in imidazolium-based ILs. However, the type of anion in imidazolium-based ILs influences the rheological properties. The performance of ionic liquids was compared with that of the commonly used clay inhibitor (sodium silicate) in the oil and gas industry. ILs showed improved performance compared to sodium silicate. The studied ionic liquids can be an attractive alternative for commercial clay inhibitors as their impact on the other properties of the drilling fluids was less compared to commercial inhibitors.