Multichromophore systems (MCSs) are envisioned as building blocks of molecular optoelectronic devices. While it is important to understand the characteristics of energy transfer in MCSs, the effect of multiple donors on energy transfer has not been understood completely, mainly due to the lack of a platform to investigate such an effect systematically. Here, a systematic study on how the number of donors (n D) and interchromophore distances affect the efficiency of energy transfer (η FRET) is presented. Specifically, η FRET is calculated for a series of model MCSs using simulations, a series of multiporphyrin dendrimers with systematic variation of n D and interdonor distances is synthesized, and η FRETs of those dendrimers using transient absorption spectroscopy are measured. The simulations predict η FRET in the multiporphyrin dendrimers well. In particular, it is found that η FRET is enhanced by donor-to-donor energy transfer only when structural heterogeneity exists in an MCS, and the relationships between the η FRET enhancement and the structural parameters of the MCS are revealed.
Keywords: Förster resonance energy transfer (FRET); energy transfer; light harvesting; multichromophore systems.
© 2020 The Authors. Published by Wiley‐VCH GmbH.