Herein, a concise overview of the use of heavier main group elements in multicomponent reactions and their use in polymer chemistry is provided. Incorporating heavier elements into macromolecular structures via multicomponent reactions allows for the rapid development of materials with unique properties that are not readily achieved using carbon, nitrogen, and/or oxygen. Elements in Group 13, Group 14, Group 15, and Group 16 are specifically covered examining both the familiar and unfamiliar properties of these elements and how they are used in multicomponent chemistry. Furthermore, elements that both take part in the reaction mechanism and remain in the macromolecular structure upon completion are only briefly explored. Some of the state-of-the-art work going into developing these heavier element multicomponent reactions are highlighted and it is hoped to inspire other polymer chemists to explore other parts of the periodic table.
Keywords: main group elements; multicomponent polymerizations; multicomponent reactions; postpolymerization modification.
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