The influence of urban surface type and characteristics on runoff water quality

Frances J Charters; Thomas A Cochrane; Aisling D O'Sullivan

doi:10.1016/j.scitotenv.2020.142470

The influence of urban surface type and characteristics on runoff water quality

Sci Total Environ. 2021 Feb 10;755(Pt 1):142470. doi: 10.1016/j.scitotenv.2020.142470. Epub 2020 Sep 24.

Authors

Frances J Charters¹, Thomas A Cochrane², Aisling D O'Sullivan³

Affiliations

¹ Department of Civil and Natural Resources Engineering, University of Canterbury, Private Bag 4800, Christchurch 8140, New Zealand. Electronic address: frances.charters@canterbury.ac.nz.
² Department of Civil and Natural Resources Engineering, University of Canterbury, Private Bag 4800, Christchurch 8140, New Zealand. Electronic address: tom.cochrane@canterbury.ac.nz.
³ Department of Civil and Natural Resources Engineering, University of Canterbury, Private Bag 4800, Christchurch 8140, New Zealand. Electronic address: aisling.osullivan@canterbury.ac.nz.

PMID: 33035981
DOI: 10.1016/j.scitotenv.2020.142470

Abstract

Untreated runoff was collected over multiple rain events from 19 impermeable urban surfaces, including nine roofs, six roads and four carparks, to quantify the differences in water quality due to surface type, age, condition and location. All 19 sites were exposed to the same climatic conditions. Samples were analysed for key urban pollutants of concern, namely total suspended solids and total and dissolved copper and zinc. Results showed uncoated zinc-based roofs produced zinc concentrations (up to 55 mg/L) several orders of magnitude higher than receiving environment water quality guidelines in New Zealand, of which the vast majority was in dissolved form. Even non-metallic roofs with zinc-based guttering produced zinc concentrations over ten times higher than the same roof material without zinc-based guttering. Older zinc-based roofs had approximately five times higher zinc concentrations, demonstrating a substantial age effect on the untreated runoff quality. Similarly, copper roofs produced more than an order of magnitude higher copper concentrations (up to 7.8 mg/L) above the next highest copper-producing surfaces: higher trafficked roads and carparks. Regardless of traffic volume or function, all roads and carparks produced high TSS concentrations. Dissolved metal concentrations were high across the dataset confirming that metal partitioning is an important consideration for effective pollutant control as different removal processes need to be used for dissolved versus particulate metals. This dataset provides an important benchmark of untreated runoff quality across different impermeable surface types within the same geographical area and clearly shows the influence of surface characteristics on water quality runoff regardless of the local differences in land use. These findings provide valuable guidance to stormwater managers in identifying priority surfaces and selection of appropriate treatment strategies for effective stormwater management for total suspended solids, zinc and copper.

Keywords: Copper; Dissolved metals; Impermeable surfaces; Particulate metals; Total suspended solids; Zinc.