Electrical signals produced within the human body can reveal information about a wide variety of physiological processes including physical activity, cardiac health, and psychological state. The industry standard for physiological signal detection is the use of adhesive electrodes that stick onto the skin. These electrodes can irritate the skin over long periods of time and are not reusable, making them a challenge for use in operational environments. Further, these electrodes often require gel to improve signal transduction, leading to changes in signal quality as these gels dry over time. Wearable sensors for operational environments should be comfortable, unobtrusive, and non-stigmatizing while maintaining signal quality high enough to allow the detection of health states. Here, we present the development and test of a set of woven textile electrodes of 8 different sizes for chest-mounted, 3-lead electrocardiogram (ECG) monitoring. Ten male subjects were tested with each of the woven electrode sizes and with one set of adhesive electrodes. A derived performance metric and signal-to-noise ratio were calculated for each set of electrodes for comparison between them. The smallest sized electrodes were found to be least effective, while the 6th of the 8 sizes were found to be most effective.