Structural and thermodynamic properties of hard-sphere fluids

J Chem Phys. 2020 Sep 28;153(12):120901. doi: 10.1063/5.0023903.

Abstract

This Perspective article provides an overview of some of our analytical approaches to the computation of the structural and thermodynamic properties of single-component and multicomponent hard-sphere fluids. For the structural properties, they yield a thermodynamically consistent formulation, thus improving and extending the known analytical results of the Percus-Yevick theory. Approximate expressions linking the equation of state of the single-component fluid to the one of the multicomponent mixtures are also discussed.