This paper analyzes the digital modelling of radiance reflectance of the sea surface when the water column is polluted by oil-in-water emulsion. A method tracking the fate of two billion virtual solar photons was applied to obtain the angular distribution of bottom-up radiance for a plane of sunlight striking the sea surface. For the calculations, the inherent optical properties of seawater characteristic for the Gulf of Gdańsk (southern Baltic Sea) were used. The analyses were performed for two types of oils with extremely different optical properties for an oil concentration of 10 ppm and for a roughened sea surface with a wind speed of 2 m/s. The spectral index for oil detection in seawater for different viewing angles was determined based on the results obtained for reflectance at eight wavelengths in the range of 412-676 nm for viewing angle in the range from 80° to 0°, both on the side of incidence of direct sunlight and on the opposite side. The resulting calculated spectral indexes for different wavelength combinations indicated significant dependence on the viewing angle.
Keywords: oil detection; oil-in-seawater emulsion; radiance reflectance; spectral index; sun glints.